Main Difference
The main difference between Pentagon and Hexagon is that the Pentagon is a polygon with five sides and Hexagon is a polygon with six sides.
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Pentagon
In geometry, a pentagon (from the Greek πέντε pente and γωνία gonia, meaning five and angle) is any five-sided polygon or 5-gon. The sum of the internal angles in a simple pentagon is 540°.
A pentagon may be simple or self-intersecting. A self-intersecting regular pentagon (or star pentagon) is called a pentagram.
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Hexagon
In geometry, a hexagon (from Greek ἕξ hex, “six” and γωνία, gonía, “corner, angle”) is a six sided polygon or 6-gon. The total of the internal angles of any hexagon is 720°.
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Pentagon (noun)
A polygon with five sides and five angles.
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Pentagon (noun)
A fort with five bastions.
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Hexagon (noun)
A polygon with six sides and six angles.
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Hexagon (noun)
a plane figure with six straight sides and angles.